INTRAMOLECULAR NUCLEOPHILIC ADDITION OF PHENOLATE TO UNACTIVATED DOUBLE AND TRIPLE BONDS. RELATIVE REACTIVITY, REGIOSPECIFICITY, STEREOCHEMISTRY, AND MECHANISM

DOI: 10.1039/P29840001269

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 1269 - 1276 (1984)

Update date:2022-08-03

Topics:

Authors:

Evans, Christopher M.

Kirby, Anthony J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P29840001269

The intramolecular nucleophilic addition of phenolate oxygen to the unactivated triple bond of a series of terminal acetylenes (11) is a two-step process, involving rate-determining formation of a vinyl carbanion.Reaction is almost 10⁴ times fa

Full text of DOI:10.1039/P29840001269

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Benzene, 2-(4,4-dibromo-1,1-dimethyl-3-butenyl)-3-methoxy-1,4-dimethyl-

Cas No:92617-99-7

R&D Labs maybe for 92617-99-7

Xinji City Taida Sinopec Co., Ltd.

Contact:0086-311-85341278

Address:No.6, Nanhua Road,Xinji City Road,Hebei Province,China
Skyrun Industrial Co.,Ltd(expird)

website:http://www.chinaskyrun.com

Contact:0086-576-84610586

Address:Chemical Development Zone
Xinjiang Zhongtai Chemical Co., Ltd.

Contact:+86-991-8788172

Address:NO.78 XISHAN RD.URUMQI，CHINA
Kunshan Yalong Trading Co,.Ltd

Contact:86-512-57621185

Address:805-807 Room Hongqiao Mansion ,1088 West Qianjin Road, Kunshan, Jiangsu，China
Anhui Biochem United Pharmaceutical Co., Ltd.

Contact:0086 551 5167062 / 5228268

Address:No. 30 Hongfeng Road, Hi-Tech Development Zone, Hefei (230088), China

Relevant to this article

Synthesis and characterization of Ni(II), Zn(II), and Cd(II) complexes with dithiophosphonate derivatives

Doi:10.1134/S1070328406060078
(2006)
Novel 1,2,3-Thiadiazolyl Sulfines from the Reaction of N-Substituted Hydrazones with Thionyl Chloride

Doi:10.1021/jo00199a006
(1984)
Doi:10.1021/ja01332a045
(1933)
4,5-Dihydrothiazoline - A new protecting and activating group for generation of α-aminocarbanions of secondary amines

Doi:10.1080/00397910600941331
(2006)
Preliminary studies on a novel synthesis of β-amino acids: stereocontrolled transformation of d- and l-glyceraldehyde into 3-amino-2-(2′,2′-dimethyl-1′,3′-dioxolan- 4′-yl)propanoic acids

Doi:10.1016/j.tetasy.2006.11.037
(2006)
π² instead of σ²) and unusual transannular metal-carbene interactions (π_C→Pd donation and σ_Pd→C bac">Transient palladadiphosphanylcarbenes: Singlet carbenes with an "Inverse" electronic configuration (p_π² instead of σ²) and unusual transannular metal-carbene interactions (π_C→Pd donation and σ_Pd→C bac

Doi:10.1021/ja066738j
(2007)

Article Doi