INTRAMOLECULAR NUCLEOPHILIC ADDITION OF PHENOLATE TO UNACTIVATED DOUBLE AND TRIPLE BONDS. RELATIVE REACTIVITY, REGIOSPECIFICITY, STEREOCHEMISTRY, AND MECHANISM

DOI: 10.1039/P29840001269

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 1269 - 1276 (1984)

Update date:2022-08-03

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Authors:

Evans, Christopher M.

Kirby, Anthony J.

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Article abstract of DOI:10.1039/P29840001269

The intramolecular nucleophilic addition of phenolate oxygen to the unactivated triple bond of a series of terminal acetylenes (11) is a two-step process, involving rate-determining formation of a vinyl carbanion.Reaction is almost 10⁴ times fa

Full text of DOI:10.1039/P29840001269

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