Mechanism of the Reaction of Lithium Reagents with Esters

DOI: 10.1021/jo00215a024

Source and publish data:

Journal of Organic Chemistry p. 2715 - 2719 (1985)

Update date:2022-08-04

Topics:

Authors:

Al-Aseer, Munther A.

Allison, Bruce D.

Smith, Stanley G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00215a024

The kinetics and mechanism of the reactions of esters with alkyllithium reagents in cyclohexane and benzene have been investigated by infrared stopped-flow spectroscopy.Esters have been found to form complexes with sec-butyllithium, n-butyllithium, and cy

Full text of DOI:10.1021/jo00215a024

Products guided by the article

Product name:phenyl di sec-butylmethanol

Cas No:92860-07-6

R&D Labs maybe for 92860-07-6

Tianjin Hedong Red Cliff Chemical Reagent Factory

Contact:+86-022-84780548

Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
Zhengzhou Minzhong Pharmaceutical Co.,ltd

Contact:0086-371-65797115

Address:15/F,Jiangshan Bldg, NO.126 Huanghe Road,Zhengzhou, China
Ji'nan Orgachem Pharmaceutical Co.,Ltd

Contact:+86-531-82687810

Address:Jinan
Jining Shengrun Chemical Industry Co., Ltd.

Contact:+86-537-7121666 ,

Address:West Ring Road,Wenshang County Shandong Province
Tianjin Crest Pharmaceutical R&D Co., Ltd. （Tianjin Yao Technology Development Co., Ltd.）(expird)

Contact:+86-22-66211386

Address:Building B5-405, No, 80 4th Avenue, TEDA, Tianjin, China P.R. 300457

Relevant to this article

Enantioselective synthesis of levomilnacipran

Doi:10.1039/c2cc33743f
(2012)
Diastereoface-discrimination reaction of lithium or titanium ester enolates with a chiral imine leading to stereodivergent synthesis of β-lactams

Doi:10.1016/0040-4020(92)80013-6
(1992)
Base-Promoted Double-Bond-Migration/Hydrolysis/Isomerization of 4-Aryl-1,1,1-trifluorobut-2-en-2-yl Trifluoromethanesulfonates: A Metal-Free Approach to β-Trifluoromethyl Ketones

Doi:10.1002/ejoc.201801025
(2018)
One-pot, three-component reaction of dimedone, amines, and isatin in the presence of tris(hydrogensulfato) boron: Synthesis of pyrroloacridine derivatives

Doi:10.1007/s11164-014-1576-y
(2015)
Influence of strain on chemical reactivity. Relative reactivity of torsionally distorted double bonds in MCPBA epoxidations

Doi:10.1021/ja00034a042
(1992)
Photodegradation of oxytocin and thermal stability of photoproducts

Doi:10.1002/jps.23204
(2012)

Article Doi