PCET-Based Ligand Limits Charge Recombination with an Ir(III) Photoredox Catalyst

DOI: 10.1021/jacs.1c01701

Source and publish data:

Journal of the American Chemical Society p. 13034 - 13043 (2021)

Update date:2022-07-30

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Authors:

Heredia, Daniel A.

Knowles, Robert R.

Moore, Ana L.

Moore, Thomas A.

Odella, Emmanuel

Ripberger, Hunter H.

Rumbles, Garry

Sayre, Hannah

Scholes, Gregory D.

Zieleniewska, Anna

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Article abstract of DOI:10.1021/jacs.1c01701

Upon photoinitiated electron transfer, charge recombination limits the quantum yield of photoredox reactions for which the rates for the forward reaction and back electron transfer are competitive. Taking inspiration from a proton-coupled electron transfe

Full text of DOI:10.1021/jacs.1c01701

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