Total Synthesis of (+)-Pipoxide and (+)-β-Senepoxide and Their Diene Precursors

DOI: 10.1021/jo00213a030

Source and publish data:

Journal of Organic Chemistry p. 2356 - 2359 (1985)

Update date:2022-08-03

Topics:

Authors:

Ogawa, Seiichiro

Takagaki, Tohei

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Article abstract of DOI:10.1021/jo00213a030

(2R)-trans-2,3-Diacetoxy-1-<(benzoyloxy)methyl>cyclohexa-4,6-diene (6), a diene precursor in the biosynthesis of highly oxygenated cyclohexane epoxides, has first been totally synthesized from the bromo lactone 16 derived from (1S)-endo-7-oxabicyclo<2.2.1

Full text of DOI:10.1021/jo00213a030

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