
Tetrahedron Letters p. 1053 - 1056 (1985)
Update date:2022-08-03
Topics:
Mloston, Grzegorz
Huisgen, Rolf
The surprising formation of C22H32N2S2 from the title compound 1 at 45 oC involves the interaction of the basic adamantanethione S-methylide (2) with its acidic precursor 1, in the course of which the anion 6 undergoes electrocyclic ring opening; the acid and base functions offer the clue to a prolific chemistry of the thiadiazoline 1 and the thiocarbonyl ylide 2.
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