Organometallics p. 821 - 823 (1984)
Update date:2022-08-05
Topics:
Fackler Jr., John P.
Murray
Basil, John D.
In addition to establishing the reversible nature of the oxidative addition of RX (R = CH3, CD3; X = Br, I) to [Au(CH2)2PPh2]2, we have observed that [Au(CH2)2PPh2]2 catalyzes halogen exchange between CH3Br and CD3I as well as between [Au(CH2)2PPh2]2Br2 and CH3I in CDCl3. The results of attempted halogen exchange with a variety of alkyl halides suggests that a SN2 process is likely via the formation of [[Au(CH2)2PPh2]2CH3] +I-; thus the dinuclear gold(I) complex effects exchange by ionization of CH3I.
website:http://www.tbbmed.com
Contact:86--21-50498136
Address:Room 6002, Building 7-1, No.160 Basheng Road,Pudong Area,Shanghai China
Contact:+49-4101-3053-0
Address:Waldhofstrasse 14 ,25474 Ellerbek Germany
Taizhou Green Peptide Trading Co., Ltd.
Contact:13736652831
Address:Room 1501, No71, Yuehe Road, Taizhou City, Zhejiang Province, China
Feis International Trade Co,. Ltd
Contact:13961823444-18235944442
Address:Wuxi jiangsu
website:http://www.uvchemkeys.com
Contact:0086-021-58785816
Address:RM2607 Building No.1 Guosheng, Lane 388, Zhongjiang Road, Putuo District, Shanghai 200062 China
Doi:10.1016/j.bmc.2012.10.052
(2013)Doi:10.1021/ml500533x
(2015)Doi:10.1016/j.tetlet.2010.07.041
(2010)Doi:10.1016/j.bmcl.2010.04.119
(2010)Doi:10.3762/bjoc.6.103
(2010)Doi:10.1016/j.tetasy.2010.04.034
(2010)
