Organometallics p. 821 - 823 (1984)
Update date:2022-08-05
Topics:
Fackler Jr., John P.
Murray
Basil, John D.
In addition to establishing the reversible nature of the oxidative addition of RX (R = CH3, CD3; X = Br, I) to [Au(CH2)2PPh2]2, we have observed that [Au(CH2)2PPh2]2 catalyzes halogen exchange between CH3Br and CD3I as well as between [Au(CH2)2PPh2]2Br2 and CH3I in CDCl3. The results of attempted halogen exchange with a variety of alkyl halides suggests that a SN2 process is likely via the formation of [[Au(CH2)2PPh2]2CH3] +I-; thus the dinuclear gold(I) complex effects exchange by ionization of CH3I.
Ceresking Ecology & Technology co.,ltd
Contact:86 22 66218397
Address:Room 1613, Zheshang Mansion, No. 1988, Yingbin Avenue, Binhai New District, Tianjin,China.
Contact:(86) 731 88718666
Address:Room 1222, Unit 4, Building B, Shangcheng, No.47, Kaiyuan East Road.
Disynthesis Chemical Technology Co. Ltd.
Contact:+86-571-88194596
Address:Dengyun road 380, Gongshu district, Hangzhou city, China
Beijing Wisdom Chemicals Co., Ltd.
Contact:+86-10-52350335
Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China
SINO Industries Company Limited(expird)
Contact:86-29-85369724
Address:No.111, Jiefang Road, Xi’an, China
Doi:10.1016/j.bmc.2012.10.052
(2013)Doi:10.1021/ml500533x
(2015)Doi:10.1016/j.tetlet.2010.07.041
(2010)Doi:10.1016/j.bmcl.2010.04.119
(2010)Doi:10.3762/bjoc.6.103
(2010)Doi:10.1016/j.tetasy.2010.04.034
(2010)
