Tetrahedron Letters p. 607 - 610 (1985)
Update date:2022-08-04
Topics:
Brown, William L.
Fallis, Alex G.
General methods for inverting the stereochemistry of vinyl tertiary-alcohols such as 2 and 5 into 3 and 8 respectively are described.The procedures employ a <2,3> sulfoxide rearrangement and will facilitate the extended use of the oxy-Cope rearrangement to a variety of related ring systems.
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