A convenient two-step procedure for the synthesis of di- and trisubstituted α-nitroalkenes from tertiary β-nitro alcohols

Article abstract of DOI:10.1080/00397919608003835

Treatment of tertiary β-nitro alcohols I, obtained by addition of lithium α-lithionitronates to ketones, with acetic anhydride followed by 1 equivalent of potassium methoxide or t-butoxide, according to the nature of R², gives α-nitroalkenes II

Full text of DOI:10.1080/00397919608003835

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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A Convenient Two-Step
Procedure for the Synthesis
of DI-and Trisubstituted α-
Nitroalkenes from Tertiary β-
Nitro Alcohols
J.C. Ferrand a , R. Schneider a , P. Gérardin a & B.
Loubinoux a
a LERMAB, Laboratoire de Chimie Organique 4,
Université Henri-Poincaré, Nancy-I, Faculté des
Sciences, BP 239, 54506, Vandoeuvre-les-Nancy,
France
Version of record first published: 23 Aug 2006
To cite this article: J.C. Ferrand, R. Schneider, P. Gérardin & B. Loubinoux (1996):
A Convenient Two-Step Procedure for the Synthesis of DI-and Trisubstituted
α-Nitroalkenes from Tertiary β-Nitro Alcohols, Synthetic Communications: An
International Journal for Rapid Communication of Synthetic Organic Chemistry, 26:23,
4329-4336
To link to this article: http://dx.doi.org/10.1080/00397919608003835
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