ASYMMETRIC INDUCTION IN THE SIGMATROPIC REARRANGEMENT VIA SULFUR YLIDES DERIVED FROM CHIRAL KETENIMINES

DOI: 10.1246/cl.1982.1871

Source and publish data:

Chemistry Letters p. 1871 - 1874 (1982)

Update date:2022-08-04

Topics: Asymmetric Induction SULFUR YLIDES

Authors:

Hiroi, Kunio

Sato, Shuko

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Article abstract of DOI:10.1246/cl.1982.1871

The asymmetric <2,3> sigmatropic rearrangement of 2-alkylamino-3-phenyl-2-pentenylmethylsulfonium methylide (4) was accomplished by reaction of ethylphenylketenimines 2, having chiral carbons next to the nitrogen atoms, with trimethylsulfonium ylide (3) a

Full text of DOI:10.1246/cl.1982.1871

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