ASYMMETRIC INDUCTION IN THE SIGMATROPIC REARRANGEMENT VIA SULFUR YLIDES DERIVED FROM CHIRAL KETENIMINES

DOI: 10.1246/cl.1982.1871

Source and publish data:

Chemistry Letters p. 1871 - 1874 (1982)

Update date:2022-08-04

Topics: Asymmetric Induction SULFUR YLIDES

Authors:

Hiroi, Kunio

Sato, Shuko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1982.1871

The asymmetric <2,3> sigmatropic rearrangement of 2-alkylamino-3-phenyl-2-pentenylmethylsulfonium methylide (4) was accomplished by reaction of ethylphenylketenimines 2, having chiral carbons next to the nitrogen atoms, with trimethylsulfonium ylide (3) a

Full text of DOI:10.1246/cl.1982.1871

Products guided by the article

Product name:N-(S)-sec-butyl-2-phenylbutyrimidoyl chloride

Cas No:99306-90-8

R&D Labs maybe for 99306-90-8

Changzhou LanXu Chemical Co.,ltd.(expird)

Contact:86-0519-86330911,13656129734,15261186386

Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China
Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

website:http://www.jlpharms.com

Contact:86-571-86982636

Address:Rm A606, Fuyi Center, jianqiao street
Hangzhou Haichem Co.,Ltd.

Contact:+86-571-86025531 / 86024803

Address:1218-24 Guangyin Mansion,42 Fengqi East Road
Huzhou City Linghu Xinwang Chemical Co.,Ltd.

Contact:86-572-3948695/3945236

Address:huzhou
Laizhou City Laiyu Chemical CO.,Ltd

Contact:+86-535-2719337/2719339

Address:Chenggang road zhuyou laizhou City Shangdong China

Relevant to this article

5-HT₁ and 5-HT₂ Binding Characteristics of 1-(2,5-Dimethoxy-4-bromophenyl)-2-aminopropane Analogues

Doi:10.1021/jm00152a005
(1986)
Metal-Nitroxyl Interactions. 46. EPR Spectra of Low-Spin Iron(III) Complexes of Spin-Labeled Tetraphenylporphyrins and Their Implications for the Interpretation of EPR Spectra of Spin-Labeled Cytochrome P450

Doi:10.1021/ja00264a010
(1986)
Synthesis and absolute configuation of (+)-Gonyauline: A modulating substance of bioluminescent circardian rhythm in the unicellular alga gonyaulaux polyedra

Doi:10.1016/S0040-4039(00)78868-X
(1992)
Synthesis and insecticidal activity of an oxabicyclolactone and novel pyrethroids

Doi:10.3390/molecules171213989
(2012)
Metal-free C-H thioarylation of arenes using sulfoxides: A direct, general diaryl sulfide synthesis

Doi:10.1039/c6cc07627k
(2016)
A ring-closing metathesis approach to heterocycle-fused azepines

Doi:10.1016/j.tetlet.2012.12.042
(2013)

Article Doi