Electrochemical Generation of Reactive Nitrogen Species. 10. Anodic Amination of Tetrahydrofuran

DOI: 10.1021/jo00353a018

Source and publish data:

Journal of Organic Chemistry p. 366 - 369 (1986)

Update date:2022-08-04

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Authors:

Fuchigami, Toshio

Sato, Takashi

Nonaka, Tsutomu

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Article abstract of DOI:10.1021/jo00353a018

Anodic oxidation in THF of aminyl anions (lithium amides and aminomagnesium bromides) together with free aliphatic amines efficiently afforded 2-aminotetrahydrofurans.A similar reaction took place in the anodic oxidation of N-lithiolactams.These reactions are the first examples of anodic amination of an aliphatic saturated ether.

Full text of DOI:10.1021/jo00353a018

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