TRANSFORMATION OF ACYLOIN O-ACYL DERIVATIVES TO KETONES USING TETRABUTYLAMMONIUM FLUORIDE-THIOL SYSTEM

DOI: 10.1016/0040-4039(95)01597-3

Source and publish data:

Tetrahedron Letters p. 7467 - 7470 (1995)

Update date:2022-08-11

Topics:

Authors:

Ueki, Masaaki

Okamura, Ayako

Yamaguchi, Jun-ichi

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Article abstract of DOI:10.1016/0040-4039(95)01597-3

The treatment of acyloin (α-hydroxyketone) O-acyl derivatives with tetrabutylammonium fluoride hydrate (TBAF*xH2O)-1,3-propanedithiol system gave the corresponding ketones.Further, it was found that N-methylmorpholine added could prevent the concomitant of unidentified compounds to give the pure products in high yields.

Full text of DOI:10.1016/0040-4039(95)01597-3

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