Journal of Organic Chemistry p. 5075 - 5077 (1992)
Update date:2022-08-11
Topics:
O'Connor, Joseph M.
Ma, Junning
The metal-catalyzed decarbonylation of primary aldehydes has been achieved at room temperature in THF solvent by utilization of catalytic amounts of Rh(PPh3)3Cl (2, 5 mol percent), in conjunction with stoichiometric amounts of diphenylphosphoryl azide (DPPA, 4).
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