Journal of the Chemical Society. Chemical communications p. 92 - 93 (1985)
Update date:2022-08-16
Topics:
Suggs, J. William
Jun, Chul-Ho
8-Quinolinyl alkyl ketones, in which the alkyl group has β-hydrogens, react with various Rh(I) and Ir(I) complexes under ethylene to give, in a catalytic process, 8-quinolinyl ethyl ketone; the same reaction with 8-quinolinyl phenyl ketone produces styrene via ethylene insertion into a rhodium-phenyl bond and β-elimination of the resulting phenylethyl complex.
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