Reactions of vinyldisilanes with ruthenium carbonyl

DOI: 10.1246/cl.1999.717

Source and publish data:

Chemistry Letters p. 717 - 718 (1999)

Update date:2022-08-29

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Authors:

Dai, Xiaosu

Kano, Naokazu

Kako, Masahiro

Nakadaira, Yasuhiro

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Article abstract of DOI:10.1246/cl.1999.717

Reaction of β-styrylpentamethyldisilane (1a) with Ru₃(CO)₁₂ afforded β-styryltrimethylsilane (2a) with elimination of a dimethylsilylene unit, while under similar conditions α-isomer 1b yielded 2a together with 1a. Studies on these r

Full text of DOI:10.1246/cl.1999.717

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