Inorganic Chemistry
Article
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hydrogen abstraction. Available data reveal that adding redox-
inactive metal ions would greatly accelerate the electron
transfer rate of the manganese(IV) complexes in sulfoxidations
and triphenylphosphine oxygenation, and its ability in electron
transfer was also promoted as well. Similar accelerations have
also been found in catalytic sulfide oxidations with the
corresponding manganese(II) complexes as catalyst and PhIO
as oxidant. Significantly, the improved efficiency in electron
transfer is highly dependent on the Lewis-acid strength of the
added metal ions. Compared with those in electron transfer,
oxygen transfer and hydrogen abstraction efficiencies of the
manganese complexes in stoichiometric and/or catalytic
oxidations are just slightly improved by adding redox-inactive
metal ions. However, the thermodynamic driving force of the
manganese(IV) species in hydrogen abstraction has been
obviously promoted. The improved oxidizing capability of the
manganese(IV) species has been attributed to its interaction
with the added redox-inactive metal ions through the plausible
MnIV−O−Al3+ bridge, which increases the overall net charge of
the manganese(IV) species, thus increasing its redox potential.
The comprehensive study demonstrated here on the influences
of the redox-inactive metal ions on the stoichiometric and
catalytic oxidations of these manganese complexes may provide
new clues to the best understanding of their roles in versatile
biological and chemical oxidations and benefit the rational
design of novel oxidation catalysts.
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ASSOCIATED CONTENT
* Supporting Information
■
S
UV−vis spectra of the manganese(IV) complexes with different
Lewis acid in dry acetone; detailed kinetic data for oxygenations
of triphenylphosphine and substituted triarylphosphine by
manganese(IV) complexes in the presence of Lewis acid; GC-
MS graphs of the C−S cleavage products of benzyl phenyl
sulfide in quantitative and catalytic oxidations. This material is
AUTHOR INFORMATION
Corresponding Author
Notes
■
The authors declare no competing financial interest.
(12) Leeladee, P.; Baglia, R. A.; Prokop, K. A.; Latifi, R.; de Visser, S.
P.; Goldberg, D. P. J. Am. Chem. Soc. 2012, 134, 10397.
(13) Park, Y. J.; Ziller, J. W.; Borovik, A. S. J. Am. Chem. Soc. 2011,
133, 9258.
ACKNOWLEDGMENTS
■
This work was supported by the National Natural Science
Foundation of China (Nos. 20973069 and 21273086). GC-MS
analysis was performed in the Analytical and Testing Center of
Huazhong University of Science and Technology.
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