Synthesis and Properties of a Methyl Derivative of Zeise's Dimer

DOI: 10.1039/c39840000193

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 193 - 195 (1984)

Update date:2022-08-11

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Authors:

Scott, John D.

Puddephatt, Richard J.

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Article abstract of DOI:10.1039/c39840000193

A methyl(ethylene)platinum(II) complex has been prepared and characterized; it forms complexes where L = pyridine, Me2S, or C2H4, undergoes exchange with unsaturated reagents (un) where (un) = PhCH=CHPh, CH(CO2Me)=CH(CO2Me), or PhCCPh to give , undergoes insertion with CF3CCCF3 to give, after treatment with pyridine, (py)2>, and reacts with Zeise's dimer to give the unsymmetrical dimer .

Full text of DOI:10.1039/c39840000193

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