Regioselectivity in the Addition of Carbon Nucleophiles to 1-Fluoro and 1,1-Difluoro ?-Allylpalladium Complexes

Article abstract of DOI:10.1016/0040-4039(95)01278-P

Attack on 1-fluoro and 1,1-difluoro ?-allylpalladium complexes by stabilized carbon nucleophiles occurs preferentially at the nonfluorinated terminus, whereas the attack of a nonstabilized carbon nucleophile takes place at the fluorinated end.