Regioselectivity in the Addition of Carbon Nucleophiles to 1-Fluoro and 1,1-Difluoro ?-Allylpalladium Complexes

DOI: 10.1016/0040-4039(95)01278-P

Source and publish data:

Tetrahedron Letters p. 6305 - 6308 (1995)

Update date:2022-08-16

Topics:

Authors:

Shi, Guo-quiang

Huang, Xian-hai

Zhang, Fang-Jiang

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Article abstract of DOI:10.1016/0040-4039(95)01278-P

Attack on 1-fluoro and 1,1-difluoro ?-allylpalladium complexes by stabilized carbon nucleophiles occurs preferentially at the nonfluorinated terminus, whereas the attack of a nonstabilized carbon nucleophile takes place at the fluorinated end.

Full text of DOI:10.1016/0040-4039(95)01278-P

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