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Reactivity of Alkenes at a Diruthenium Centre: Carbon-Carbon Bond Formation via HF Elimination

DOI: 10.1039/c39890000640

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 640 - 642 (1989)

Update date:2022-08-30

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Authors:

Howard, Judith A. K.Howard, Judith A. K.

Knox, Selby A. R.Knox, Selby A. R.

Terrill, Nicholas J.Terrill, Nicholas J.

Yates, Michael I.Yates, Michael I.

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Article abstract of DOI:10.1039/c39890000640

N.m.r. spectra and X-ray diffraction indicate the presence of intramolecular H...F hydrogen bonding between the methylene and alkene ligands in the complexes (R=F or CF3); methylene-alkene combination occurs via HF elimination under mild conditions, giving .

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