CATALYTIC REGIOSELECTIVE DEHYDROGENATION OF UNSYMMETRICAL α,ω-DIOLS USING RUTHENIUM COMPLEXES

DOI: 10.1016/S0040-4039(00)87975-7

Source and publish data:

Tetrahedron Letters p. 2677 - 2680 (1983)

Update date:2022-08-11

Topics:

Authors:

Ishii, Youichi

Osakada, Kohtaro

Ikariya, Takao

Saburi, Masahiko

Yoshikawa, Sadao

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Article abstract of DOI:10.1016/S0040-4039(00)87975-7

Ruthenium complex catalyzed regioselective dehydrogenation of unsymmetrically substituted 1,4- and 1,5-diols in the presence of α,β-unsaturated ketone as a hydrogen acceptor and triethylamine gave β-substituted γ-lactones and γ-substituted δ-lactones as major products, respectively.

Full text of DOI:10.1016/S0040-4039(00)87975-7

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