Tetrahedron Letters p. 507 - 510 (1990)
Update date:2022-08-11
Topics:
Kauffmann, Thomas
Laarmann, Barbara
Menges, Detlef
Voss, Karl-Uwe
Wingbermuehle, Dorothea
Nonstabilized Fe(II) alkyls (RFeCl, R2Fe, R3FeM, R4FeM2; R=Me, n-Bu, M=Li, MgBr) are readily accessible in solution (THF, Et2O, CH2Cl2) by reaction of MeLi, MeMgBr, n-BuLi or n-BuMgBr, respectively, with FeCl2 at -78 to -50 deg C.The needed FeCl2 can be made by in-situ-reduction with RLi or RMgBr.For checking the transmetallation process the "β-bromostyrene-ketone-test" is especially favorable in case of the methyl derivatives.The prepared Fe compounds are alkylating reagents of high selectivity.
View More
website:http://www.vanzpharm.com/en/index.html
Contact:86-27-84492310
Address:FANHU INDUSTRY PARK
Contact:+36(21)2523420
Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
HANGZHOU EVC CHEMICAL CO.,LTD.(expird)
Contact:+86-571-88296056
Address:Room#3001,Zhejiang Chemical Market,No.10,Road Shenban,Hangzhou,Zhejiang,China
HANGZHOU TOYOND BIOTECH CO., LTD
Contact:+86-571-86965177
Address:No. 189, Fengqi East Road, Hangzhou, China
website:http://www.vanzpharm.com/en/index.html
Contact:86-27-84492310
Address:FANHU INDUSTRY PARK
Doi:10.1016/j.saa.2015.03.113
(2015)Doi:10.1016/j.tetlet.2007.08.088
(2007)Doi:10.1080/14756366.2020.1740695
(2020)Doi:10.1016/S0009-2614(99)00586-2
(1999)Doi:10.1021/np900266m
(2009)Doi:10.1007/BF00810777
(1997)
