Journal of Organic Chemistry p. 1228 - 1230 (1984)
Update date:2022-08-11
Topics:
Davis, Franklin A.
Panunto, Thomas W.
Awad, Sami B.
Billmers, Robert L.
Squires, Thomas G.
The primary pyrolysis reaction of sulfides, sulfoxides, and sulfones (1-3), in the gas phase at 500 - 900 deg C, is homolytic cleavage of the C-SOn bond.The order of reactivity, sulfoxide >> sulfone > sulfide, is consistent with the relative stabilities of the radicals produced.At 900 deg C a novel and synthetically useful rearrangement of dibenzothiophene 5-oxide (3b) to 1-hydroxydibenzothiophene (5) was observed.
View More
Nanjing Samwon International Limited
Contact:+86-25-84873444
Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
Taizhou volsen chemical Co., Ltd
website:http://www.volsenchem.com
Contact:+86-576-88869393
Address:Jiaojiang District, Taizhou, Zhejiang, China.
Tianjin SPHINX SCIENTIFIC LAB.
Contact:+86-022-66211289
Address:Tianda high-tech Park. No.80,the 4th Avenue
Sichuan Highlight Fine Chemicals Co., Ltd.
Contact:+86-28-8525 1605
Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section
Contact:18698110882
Address:1303 No2 building,LuoMa Garden,YongAn Road,Hexi District,Tianjin city
Doi:10.1007/s10973-016-5805-z
(2017)Doi:10.1039/c9sc02792k
(2019)Doi:10.1021/jo01291a029
(1980)Doi:10.1021/jacs.6b11023
(2017)Doi:10.1016/j.bmc.2011.07.058
(2011)Doi:10.1021/jacs.6b04501
(2016)
