Preparation of Some Metallodithiocarboxylato- and Metallodithiocarbene-metal Complexes

DOI: 10.1039/DT9820001631

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1631 - 1634 (1982)

Update date:2022-08-11

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Authors:

Busetto, Luigi

Palazzi, Antonio

Monari, Magda

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Article abstract of DOI:10.1039/DT9820001631

The reaction between the carbon disulphide adduct of dicarbonyl(cyclopentadienyl)iron, <(cp)(CO)2FeCS2>(1+) (cp=η⁵-C5H5), and (M=Mn or Re) produces in good yield the heterodinuclear complexes <(cp)(CO)2FeCS2M(CO)4> in which the CS2 group acts as a bridge in the unit FeC(=S)SM.Depending on the reaction conditions, both the chelato-complex <(cp)(CO)2FeC(=S)SRe(CO)4> and the unidentate <(cp)(CO)2FeC(=S)SRe(CO)5> derivative are obtained.Alkylation of the thione sulphur atom in the unit FeC(=S)SRe produces the dithiocarbene <(cp)(CO)2FeC(SCH3)SRe(CO)5>(1+) in good yield.The reaction of this metallodithiocarbenemetal complex with methylamine yields <(cp)(CO)2FeC(=S)(SCH3)> and .The compounds <(cp)(CO)2FeC(=S)(SCH3)> and were formed from the reaction of <(cp)(CO)2FeC(SCH3)SRe(CO)5>(1+) with LiBr.

Full text of DOI:10.1039/DT9820001631

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