
Journal of the Chemical Society. Perkin transactions I p. 2545 - 2549 (1983)
Update date:2022-08-12
Topics:
Mellor, John M.
Pathirana, Ranjith
Reduction of the anti-Bredt bishydrazone 4,9-dimethyl-2,3,7,8-tetra-azatetracyclo<7.3.1.0.4,1206,10>trideca-1,6-diene with lithium aluminium hydride-aluminium chloride or by catalytic hydrogenation gives the bishydrazine 1,6-dimethyl-2,3,7,8-tetra-azatetracyclo<7.3.1.0.4,1206,10>tridecane, but reaction with either lithium aluminium hydride or aluminium chloride gives dihydropyrazoles by ring cleavage.
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