Reagent control in the aldol addition reaction of chiral boron enolates with chiral aldehydes

DOI: 10.1016/S0040-4039(00)60746-3

Source and publish data:

Tetrahedron Letters p. 4623 - 4626 (1994)

Update date:2022-08-28

Topics:

Authors:

Gennari, Cesare

Moresca, Daniela

Vulpetti, Anna

Pain, Gilles

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Article abstract of DOI:10.1016/S0040-4039(00)60746-3

Boron enolates bearing menthone-derived chiral ligands are capable of fair to excellent diastereocontrol in their reactions with chiral aldehydes. Thioester-derived (better than ketone derived) enolates are able to control aldol stereochemistry irrespective of the aldehyde preferences.

Full text of DOI:10.1016/S0040-4039(00)60746-3

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