Journal of the Chemical Society. Chemical communications p. 572 - 573 (1985)
Update date:2022-08-11
Topics:
Fischer, Helmut
Schmid, Johann
Maerkl, Robert
The benzylidene complexes (CO)5W=CH(p-C6H4R) (R = H, Me) react with diethyl ether or tetrahydrofuran to give regiospecifically the products of the insertion of the benzylidene ligand into the α-C-H bond of the ethers; the insertion reaction follows an associative mechanism initiated by a nucleophilic attack of the ethers at the benzylidene ligand.
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