Inversion of the relative reactivities and selectivities of benzyl chloride and benzyl alcohol in friedel-crafts alkylation with toluene using different solid acid catalysts: An adsorption related phenomenon

DOI: 10.1016/0040-4039(93)85119-H

Source and publish data:

Tetrahedron Letters p. 529 - 532 (1993)

Update date:2022-08-25

Topics:

Authors:

Yadav, Ganapati D.

Thorat, Tushar S.

Kumbhar, Pramod S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(93)85119-H

The Friedel-Crafts alkylation of benzyl chloride and benzyl alcohol, separately as well as in a single pot, with toluene as an alkylating agent in presence of different solid acid catalysts has been investigated to find that the inversion of relative reactivities is due to a preferential adsorption phenomenon.

Full text of DOI:10.1016/0040-4039(93)85119-H

Products guided by the article

Product name:Benzyl ether

Cas No:103-50-4

R&D Labs maybe for 103-50-4

Shenzhen Hongyuan Import & Export Co., Ltd.

Contact:0755-26407171

Address:Shenzhen Hongyuan Chemical New Materials Technology Co., Ltd.
Shandong LuZhou Amino Acid Co., Ltd

Contact:86-539-2218025

Address:yishui economic and technical development zone zhenxing south road
ZHEJIANG JIANYE CHEMICAL CO.,LTD.

Contact:86-571-64149273,64149234

Address:No. 48, Fuxi Road, Meicheng Town
Jiangsu Zhenfang Chemical CO.,LTD.(Suzhou Zhenfang Chemical Factory)

Contact:+86-512-69598882

Address:Room1201, Jiayuan Road No.1018, Xiangcheng District, Suzhou, China
HaiNan Periwinkle Pharmaceutical Co.,Ltd.

website:http://www.cchpharm.com/en/index.html

Contact:020-82208978

Address:Gongye road,Wuzhishan city,HaiNan province

Relevant to this article

Palladium-catalyzed debenzylative cross-coupling of aryl benzyl sulfides with aryl bromides: Synthesis of diaryl sulfides

Doi:10.1021/ol502470e
(2014)
Cyclotris(paraquat-p-phenylenes)

Doi:10.1002/anie.201907329
(2019)
Synthesis and reactivity of silyl cobalt complexes bearing a tetradentate phosphino silyl ligand via Si–H bond activation

Doi:10.1016/j.poly.2017.09.043
(2018)
Pyrazinyl ureas revisited: 1-(3-(Benzyloxy)pyrazin-2-yl)-3-(3,4-dichlorophenyl)urea, a new blocker of Aβ-induced mPTP opening for Alzheimer's disease

Doi:10.1016/j.ejmech.2018.07.068
(2018)
Synergistic effect for selective hydrodeoxygenation of anisole over Cu-ReO_x/SiO₂

Doi:10.1016/j.cattod.2020.04.034
(2021)
Copper (I) 1,3-R₂-3,4,5,6-tetrahydropyrimidin-2-ylidenes (R=mesityl, 2-propyl): Synthesis, X-ray structures, immobilization and catalytic activity

Doi:10.1016/j.tet.2005.07.116
(2005)

Article Doi