Selective reduction of hydroxy carbonyl to carbonyl compounds with trialkylborane/trifluoromethanesulfonic acid

DOI: 10.1055/s-1991-26479

Source and publish data:

Synthesis p. 407 - 408 (1991)

Update date:2022-08-11

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Authors:

Olah Olah

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Article abstract of DOI:10.1055/s-1991-26479

Triethyl- or triisopropylborane/trifluoromethanesulfonic (triflic) acid is a convenient reagent for the selective reduction of hydroxy substituted carboxylic acids, ketones and aldehydes to yield the corresponding carbonyl compounds. The scope of the reaction, experimental conditions and suggested mechanism are discussed.

Full text of DOI:10.1055/s-1991-26479

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