PARA-SELECTIVE FRIES REARRANGEMENT OF PHENYL ACETATE IN THE PRESENCE OF ZEOLITE MOLECULAR SIEVES

DOI: 10.1016/S0040-4039(00)99672-2

Source and publish data:

Tetrahedron Letters p. 2281 - 2284 (1989)

Update date:2022-08-24

Topics:

Authors:

Cundy, Colin S.

Higgins, Raymond

Kibby, Sarah A. M.

Lowe, Barrie M.

Paton, R. Michael

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Article abstract of DOI:10.1016/S0040-4039(00)99672-2

The Fries rearrangement of phenyl acetate is catalysed by acidic zeolites such as H-Nu-2 and H-ZSM-5, with selectivities of 2-6:1 in favour of para-substituted products.

Full text of DOI:10.1016/S0040-4039(00)99672-2

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