Bulletin of the Chemical Society of Japan p. 267 - 273 (1997)
Update date:2022-08-10
Topics:
Kobayashi, Shue
Moriwaki, Mitsuhiro
Hachiya, Iwao
Group 3 and 4 metal triflates (Sc(OTf)3, TiCl(OTf)3, Zr(OTf)4, and Hf(OTf)4) were found to be efficient catalysts in the Fries rearrangement of phenyl or 1 -naphthyl acylates. It was also found that the o-acylation (direct acylation) reactions of phenols and 1-naphthols with acid chlorides proceeded smoothly in the presence of the triflates. Both reactions were successfully carried out using small amounts of the triflates (catalytically), and comparison of catalytic activities of these metal triflates in these reactions is discussed.
View More
Springchem New Material Technology Co.,Limited
website:http://www.spring-chem.com
Contact:86-21-62885108
Address:602B, Building 1, No. 641, Tianshan Road
ZiBO KuoDing Trade company Ltd
website:http://www.sdzbkd.com
Contact:86-13361591822
Address:GongQingTuan road
Longhui qunfeng Chemical Co., Ltd
Contact:86-731-82173407
Address:South-east Industrial Park, Longhui County, Hunan Province, China
Changzhou Litong Chemical Co., Ltd.
website:http://www.litonchem.com/
Contact:+86-519-86301238
Address:Laoba Rd, Hutang town Changzhou Jiangsu
Hangzhou Sartort Biopharma Co., Ltd
website:http://www.sartort.com
Contact:86-571-87039693
Address:No. 57, Tech Park Road, Hangzhou, Zhejiang, China
Doi:10.1016/S0040-4039(00)86760-X
(1982)Doi:10.1246/bcsj.66.3030
(1993)Doi:10.1016/bs.mie.2020.04.060
(2020)Doi:10.1080/00397911.2016.1257724
(2017)Doi:10.1016/j.jphotobiol.2018.11.005
(2019)Doi:10.1039/c5cc01055a
(2015)
