REDUCTIVE DEHALOGENATION OF α-HALOGENATED CARBONYL AND CYANO COMPOUNDS WITH THE HEXAMETHYLDISILANE/TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM SYSTEM

DOI: 10.1016/0022-328X(82)80012-0

Source and publish data:

Journal of Organometallic Chemistry p. 367 - 374 (1982)

Update date:2022-08-17

Topics:

Authors:

Urata, Hisao

Suzuki, Hiroharu

Moro-Oka, Yoshihiko

Ikawa, Tsuneo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(82)80012-0

Treatment of α-halogenated carbonyl or cyano compounds with hexamethyldisilane in the presence of catalytic amounts of tetrakis(triphenylphosphine)-palladium gives the corresponding parent carbonyl or cyano compounds in excellent yields via oxy-?-allyl(trimethylsilyl)palladium intermediates.

Full text of DOI:10.1016/0022-328X(82)80012-0

Products guided by the article

Product name:Ethyl chloroacetate

Cas No:105-39-5

R&D Labs maybe for 105-39-5

PINGYUAN SIHUAN PHARMACEUTICAL CO., LTD

Contact:+86-531-55696072

Address:#2766,yinxiu Road, Economic Development Zone, Pingyuan Country, Shandong Province, China.
Chengda Pharmaceuticals Co., Ltd.

Contact:+86-573-84601188

Address:hengshan Road 5# in Jiashan, zhejiang
ShangHai BMG Chemical Co., Ltd

Contact:+86-13524845543

Address:Room 602, no 291 sikai road shanghai
SHIFANG SUHONG CHEMICAL CO.,LTD

Contact:+86-838-2224563

Address:Room 1207 Zongchen Sunshine No.128 Taishan South Road,Deyang City,Sichuan China
Henan Harvest Chem Co., Ltd

Contact:+86-371-86058576

Address:NO.32, Jingsan Road, Zhengzhou, China

Relevant to this article

Transition-metal-mediated activation of arylisocyanates in supercritical carbon dioxide

Doi:10.1016/S0022-328X(01)00698-2
(2001)
Structure and catalytic activity of a new iron(ii) complex with a tetradentate carboxamide ligand: The effect of the outer-sphere donor on the chemoselectivity of the metal complex catalyst

Doi:10.1134/S0036023612100129
(2012)
Highly enantioselective aza-Henry reaction promoted by amine-functionalized tridentate sulfinyl ligands

Doi:10.1016/j.tetasy.2011.05.006
(2011)
Amphiphilic Zwitterionic phosphine based Au(I)-complex as efficient and recyclable catalyst for hydration of alkynes free of additional additives

Doi:10.1016/j.mcat.2018.01.035
(2018)
Synthesis of polycyclic spiro-fused indolines via IBX-mediated cascade cyclization

Doi:10.1016/j.cclet.2020.11.001
(2021)
Perfluoroalkylated Calix[4]pyrroles: Fluoride Ion Extraction from an Aqueous Medium

Doi:10.1002/asia.201700897
(2017)

Article Doi