REDUCTIVE DEHALOGENATION OF α-HALOGENATED CARBONYL AND CYANO COMPOUNDS WITH THE HEXAMETHYLDISILANE/TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM SYSTEM

DOI: 10.1016/0022-328X(82)80012-0

Source and publish data:

Journal of Organometallic Chemistry p. 367 - 374 (1982)

Update date:2022-08-17

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Authors:

Urata, Hisao

Suzuki, Hiroharu

Moro-Oka, Yoshihiko

Ikawa, Tsuneo

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Article abstract of DOI:10.1016/0022-328X(82)80012-0

Treatment of α-halogenated carbonyl or cyano compounds with hexamethyldisilane in the presence of catalytic amounts of tetrakis(triphenylphosphine)-palladium gives the corresponding parent carbonyl or cyano compounds in excellent yields via oxy-?-allyl(trimethylsilyl)palladium intermediates.

Full text of DOI:10.1016/0022-328X(82)80012-0

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