On the mechanism of deoxygenation of secondary alcohols by tin hydride reduction of methyl xanthates and other thiocarbonyl derivatives

DOI: 10.1016/S0040-4039(00)94480-0

Source and publish data:

Tetrahedron Letters p. 3991 - 3994 (1990)

Update date:2022-08-11

Topics:

Authors:

Barton Barton

Jang Jang

Jaszberenyi Cs.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)94480-0

The room temperature deoxygenation of xanthates and thionocarbonates using (n - Bu) ₃Sn-H - Et₃B - air has been studied, especially with ¹¹⁹Sn N.M.R. spectroscopy. The orignal conception of tin radical attack on thiocarbonyl is confirmed.

Full text of DOI:10.1016/S0040-4039(00)94480-0

Products guided by the article

Product name:S-Ethyl S'-methyl dithiocarbonate

Cas No:10596-55-1

R&D Labs maybe for 10596-55-1

Hangzhou GreenCo Science & Technology Co., Ltd.

Contact:86-571-88257303

Address:1713 Room,Jingui Building,Gudun Road,Xihu District,Hangzhou,China
ShanDong XinDa Chemical CO.,LTD(expird)

Contact:086-0311-87580543

Address:No.168, High Technology Development Zone Jinan Shandong China
MINS GROUP CO.,LIMITED

Contact:18669908765

Address:Zibo City, Shandong Province, P.R.China
Dongtai Xinyuan Chemical Co., Ltd.

Contact:+86-21-56733000

Address:404F, 99Nong No.117 Zhongtan Rd. Shanghai
SYN Pharma Co., Ltd

Contact:86-21 60347964

Address:No.1304, West Meilong Road, Minhang District, Shanghai, China

Relevant to this article

Terpioside from the marine sponge Terpios sp., the first glycosphingolipid having an L-fucofuranose unit

Doi:10.1002/ejoc.200701220
(2008)
Photolysis of Methyl Vinyl Ketone at 193.3 nm: Quantum Yield Determinations of Methyl and Vinyl Radicals

Doi:10.1021/j100110a007
(1993)
Synthesis of glycerol carbonate by transesterification of glycerol and dimethyl carbonate over KF/γ-Al₂O₃ catalyst

Doi:10.5935/0103-5053.20130281
(2014)
Quantification and mass isotopomer profiling of α-keto acids in central carbon metabolism

Doi:10.1021/ac500472c
(2014)
Novel dimeric ring systems containing gallium

Doi:10.1039/cc9960002425
(1996)
Doi:10.1021/ja01297a503
(1936)

Article Doi