Journal of the American Chemical Society p. 2166 - 2171 (1987)
Update date:2022-08-16
Topics:
Frost, J. W.
Cordeiro, M. L.
Li, D.
Products resulting from the degradation of organophosphonates by Escherichia coli are identified and used as a basis for evaluating mechanisms which may be the chemical basis of the biodegradation.One mechanistic hypothesis which is consistent with the biodegradation products involves radical-based dephosphorylation.Chemical modeling of this process is achieved by the reaction of alkylphosphonic acids with lead(IV) tetraacetate and electrochemical oxidation at a platinum anode.
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