Chlorine Abstraction from Silicon-Chlorine Bonds by Trimethylsilyl Radicals

DOI: 10.1039/f19817702277

Source and publish data:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 2277 - 2280 (1981)

Update date:2022-08-22

Topics:

Authors:

Davidson, Iain M. T.

Matthews, J. Ioan

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/f19817702277

Attempts to measure the kinetics of the unusual abstraction reaction, Me3Si^. + Me2SiCl2 -> Me3SiCl + Me2Si^.Cl using thermal radical sources were unsuccessful.Kinetic data were obtained by using a photochemical radical source, yielding unconvetional Arrhenius parameters, the significance of which is discussed.

Full text of DOI:10.1039/f19817702277

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Chlorodimethylsilane

Cas No:1066-35-9

R&D Labs maybe for 1066-35-9

ZHANGJIAGANG FREE TRADE ZONE YONG HAN INTERNATIONAL TRADING CO., LTD(expird)

Contact:86 512 57910558

Address:qianjin M road
taizhou creating bio-pharm co.,ltd.

Contact:+86- 576- 88827176

Address:715 room ,unit A.junyue Building,Jiaojiang,Taizhou,Zhejiang,China
Nanjing Spring & Autumn Biological Engineering Co., Ltd.

Contact:86-180510-83338

Address:Suite# 210, No. 1 BuildingNanjing Agricultural Biotechnology High-tech Entrepreneurship Center, No. 4 Tongwei Road, Xuanwu District, Nanjing,China
Jinan Kaypharm Chemical Co.,Ltd

Contact:86-0531-86986780

Address:Room101,No189-2,Huayuan Road,Jinan City,Shandong Province
Wuhan Shengmao Corp

website:http://www.shengmaochem.com

Contact:86-27-82853423, 82819281

Address:Rm 202, A Unit Huaqiao Building No. 2, Lihuangpi Road, Wuhan, China

Relevant to this article

Chiral Synthesis via Organoboranes. 40. Selective Reductions. 55. A Simple One-Pot Synthesis of the Enantiomers of (Trifluoromethyl)oxirane. A General Synthesis in High Optical Purities of α-Trifluoromethyl Secondary Alcohols via the Ring-Cleavage Reactions of the Epoxide

Doi:10.1021/jo00106a012
(1995)
Synthesis and characterization of thiadiazolo [3,4-g]quinoxaline based π-conjugated copolymers with tunable band gaps

Doi:10.14233/ajchem.2013.14934
(2013)
Flash vacuum pyrolysis of 2-diazo-8-oxabicyclo[3.2.1]oct-6-en-3-ones. A new method for the preparation of propadienones

Doi:10.1016/S0040-4039(00)88811-5
(1990)
Impressive Structural Diversity and Polymorphism in the Modular Compounds ABi₃Q₅ (A = Rb, Cs; Q = S, Se, Te)

Doi:10.1021/ja034196p
(2003)
Doi:10.1111/j.1945-5100.2002.tb00819.x
(1956)
Photochemical fabrication of three-dimensional micro- and nano-structured surfaces from a C₆₀ monoadduct

Doi:10.1039/b718888a
(2008)

Article Doi