Phosphorus, Sulfur and Silicon and the Related Elements p. 239 - 254 (2000)
Update date:2022-08-10
Topics:
Abdreimova, Rumiya R.
Akbayeva, Dina N.
Polimbetova, Gulshara S.
Caminade, Anne-Marie
Majoral, Jean-Pierre
Oxidative alkoxylations of P4 in toluene-alcohol solutions are studied. These reactions need oxygen, a catalyst (PdCl2, RuOHCl3, RuCl3) and a co-oxidant (CuCl2, NaNO2, FeCl3, 1,4-benzoquinone, NaBrO3). Trialkylphosphates (RO)3P(O) and dialkylphosphites (RO)2P(O)H are the major products of the reaction. Kinetic experiments concerning the rate of absorption of O2 during these reactions are also reported.
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