Chlorine free synthesis of organophosphorus compounds based on the functionalization of white phosphorus (P4)

Article abstract of DOI:10.1080/10426500008045007

Oxidative alkoxylations of P₄ in toluene-alcohol solutions are studied. These reactions need oxygen, a catalyst (PdCl₂, RuOHCl₃, RuCl₃) and a co-oxidant (CuCl₂, NaNO₂, FeCl₃, 1,4-benzoquinone, NaBrO₃). Trialkylphosphates (RO)₃P(O) and dialkylphosphites (RO)₂P(O)H are the major products of the reaction. Kinetic experiments concerning the rate of absorption of O₂ during these reactions are also reported.

Full text of DOI:10.1080/10426500008045007

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Phosphorus, Sulfur, and Silicon
and the Related Elements
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CHLORINE FREE SYNTHESIS
OF ORGANOPHOSPHORUS
COMPOUNDS BASED ON THE
FUNCTIONALIZATION OF WHITE
PHOSPHORUS (P4)
Rumiya R. Abdreimova a , Dina N. Akbayeva a ,
Gulshara S. Polimbetova a , Anne-Marie Caminade a
& Jean-Pierre Majorals b
a Institute of Organic Catalysis and
Electrochemistry , 142 Kunaev St., 480100, Almaty,
Kazakhstan
b Laboratoire de Chimie de Coordination du CNRS ,
205 route de Narbonne, 31077, Toulouse cedex 4,
France
Published online: 04 Oct 2006.
To cite this article: Rumiya R. Abdreimova , Dina N. Akbayeva , Gulshara S.
Polimbetova , Anne-Marie Caminade & Jean-Pierre Majorals (2000) CHLORINE FREE
SYNTHESIS OF ORGANOPHOSPHORUS COMPOUNDS BASED ON THE FUNCTIONALIZATION
OF WHITE PHOSPHORUS (P4), Phosphorus, Sulfur, and Silicon and the Related
Elements, 156:1, 239-254, DOI: 10.1080/10426500008045007
To link to this article: http://dx.doi.org/10.1080/10426500008045007
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