An Efficient Synthesis of Optically Active 4-Methyloxetan-2-one: Asymmetric Hydrogenation of Diketene catalysed by binap-Ruthenium(II) Complexes

DOI: 10.1039/c39920001725

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1725 - 1726 (1992)

Update date:2022-08-11

Topics:

Authors:

Ohta, Tetsuo

Miyake, Tsutomu

Takaya, Hidemasa

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920001725

Highly enantioselective hydrogenation of diketene with the catalytic system derived from (benzene)>Cl and triethylamine or with Ru2Cl4<(S)- or (R)-binap>2(NEt3) in tetrahydrofuran gives optically active 4-methyloxetan-2-one in up to 97percent selectivity and 92percent enantiomeric excess (e.e.).

Full text of DOI:10.1039/c39920001725

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:n-Butanoic acid

Cas No:107-92-6

R&D Labs maybe for 107-92-6

sichuan tiancai fine co LTD.

website:http://www.tcfinechem.com/

Contact:18681346930

Address:baifu town,whou district
Ningbo Hi-tech Zone Nice-Synth Chemical Industry Ltd.

Contact:+86-(574)-81110986

Address:No. 1210, Building 3, Wante Business Centre, Hi-tech Zone, Ningbo
Wuxi Highness Chemical Co.,Ltd

website:https://www.phtpharmatech.com/

Contact:86-510-81771080

Address:No58 East Xinguan Rd, Guanlin Town, Yixing City, Jiangsu China
Meryer (Shanghai) Chemical Technology Co., Ltd.

website:http://www.meryer.com/cn/index/

Contact:+86-755-86170518

Address:Minhang,Shanghai, China
Sichuan Sangao Biochemical Co., Ltd

Contact:+86-28-84874233

Address:19F, Bldg.2, Shudu Center, Tianfu 2nd St., Hi-tech zone, Chengdu 610041, Sichuan Province, China.

Relevant to this article

Doi:10.1016/S0003-2670(00)88957-6
(1965)
Synthesis, Characterization, and Crystal Structure of (2E)-3-(4-Fluorophenyl)-1-(2-hydroxyphenyl)prop-2-en-1-one

Doi:10.1007/s10870-018-0732-4
(2018)
Photodissociation of Methyl Nitrate in a Molecular Beam

Doi:10.1021/j100144a002
(1993)
Chiral Phosphoric Acid Dual-Function Catalysis: Asymmetric Allylation with α-Vinyl Allylboron Reagents

Doi:10.1002/anie.202000039
(2020)
Use of galvanic displacement in the synthesis of a Pd(Cu) hydrodechlorination catalyst

Doi:10.1016/j.mencom.2010.01.004
(2010)
4-Substituted uridine 5′-triphosphates as agonists of the P_2y2 purinergic receptor

Doi:10.1080/07328319708006141
(1997)

Article Doi