Journal of Organic Chemistry p. 1475 - 1477 (1987)
Update date:2022-08-16
Topics:
Baldwin, John E.
Parker, David W.
An efficient synthesis of racemic methylenecyclopropaneacetic acid has been developed.A mixture of the corresponding diastereomeric coenzyme A esters, one of which is the metabolite of the nonprotein amino acid hypoglycin from Blighia sapida directly responsible for its hypoglycemic potency, reacts stereospecifically with general acyl-CoA dehydrogenase from pig kidney to irreversibly inactivate the enzyme.
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