Journal of the Chemical Society. Chemical communications p. 45 - 46 (1990)
Update date:2022-08-11
Topics:
Sorokin, Alexander B.
Khenkin, Alexander M.
High values of kinetic isotope effect (KIE), up to 21.9 +/- 1.9 at 20 deg C, are obtained in cyclohexane oxidation by an iron tetramesitylporphyrin (TMPFeCl)-hypochlorite system; their very sharp dependence on temperature suggests tunnelling contribution
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