Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 2350 - 2352 (1989)
Update date:2022-08-11
Topics:
Dzhemilev, U. M.
Ibragimov, A. G.
Morozov, A. B.
Muslukhov, R. R.
Tolstikov, G. A.
A method has been developed for the methylenation of carbonyl compounds with methylenedimagnesium iodide in the presence of Et2AlCl in 35-70percent yield.In the presence of catalytic amounts of Ti and Pd complexes the yield of methylenation products is increased by 15-20percent.
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