Journal of the American Chemical Society p. 1208 - 1212 (1982)
Update date:2022-08-16
Topics:
Velzen, P. N. T. van
Hart, W. J. van der
Greef, J. van der
Nibbering, N. M. M.
Gross, M. L.
Tautomeric phenol and 1,3-cyclohexadien-5-one radical cations exist as distinct, stable species in the gas phase.This is established by a study of the photodissociation spectra of C6H6O+. ions generated from four sources.Specifically, the ionized phenol and the C6H6O+. from phenetole exist principally as the phenol structure.On the other hand, C6H6O+. generated from bicyclo<2.2.2>oct-2-ene-5,7-dione and 2-phenoxyethyl chloride exist as a mixture of keto and enol structures.
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