Tetrahedron Letters p. 1713 - 1716 (1992)
Update date:2022-08-16
Topics:
Dauben, William G.
Cogen, Jeffrey M.
Behar, Victor
Schultz, Arthur G.
Geiss, William
Taveras, Arthur G.
The unusual wavelength dependent product selectivity observed upon irradiation of a substituted 2,5-cyclohexadien-1-one is shown to result from wavelength dependent quantum yields for rearreangement of the primary photoproduct bicyclo<3.1.0>hexenones.Reaction selectivity can be optimized by careful choice of irradiation wavelength and length of irradiation time.
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