
Inorganica Chimica Acta p. 375 - 377 (1996)
Update date:2022-08-29
Topics:
Kunkely, Horst
Vogler, Arnd
The complex C60Pt[P(OPh)3]2 displays C60 ππ* intraligand bands in the UV-Vis region and a long-wavelength absorption at λmax = 770 nm which is assigned to a metal-to-ligand charge transfer (MLCT) transition from platinum to fullerene. The irradiation of the complex leads to the population of the reactive MLCT state and subsequently to the dissociation (C60Pt[P(OPh)3]2 → C60 + Pt[P(OPh)3]2) in the primary photochemical step. Product formation takes place by the interception of Pt[P(OPh)3]2 with suitable scavengers such as CHCl3 or O2.
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