Tetrahedron Letters p. 5113 - 5116 (1992)
Update date:2022-08-24
Topics:
Lohray, Braj. B.
Bhushan, Vidya
Dihydroquinidine and dihydroquinine bisesters of malonic acid, adipic acid and terephthalic acid are used as chiral auxiliaries for osmium tetroxide catalyzed asymmetric dihydroxylation of alkenes.Highly stereoselective osmylation of alkenes has been rationalized on the basis of ?-? interaction of the alkenes with the ligand.
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