Reaction of 2-Diazopropane with an Arylsulphonyl-trimethylsilyl Substituted Alkene. Steric Control of Regiochemistry by the Trimethylsilyl Group

DOI: 10.1039/c39870001742

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1742 - 1743 (1987)

Update date:2022-08-16

Topics:

Authors:

Padwa, Albert

Wannamaker, M. Woods

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39870001742

The 1,3-dipolar cycloaddition of 2-diazopropane with trimethyl<3-(p-tolylsulphonyl-2,5-norbornadiene-2-yl)>silane occurs across the unsubstituted double bond; regiochemical control can be attributed to steric rather than to stereoelectronic factors.

Full text of DOI:10.1039/c39870001742

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:C₁₇H₂₂O₂SSi

Cas No:115134-53-7

R&D Labs maybe for 115134-53-7

Sinonine Industry Co.,Ltd

Contact:86+21-56421993

Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.
Rudong Zhenfeng Yiyang Chemical Co., Ltd.

Contact:0513-84573047

Address:South Fengli Town, Rudong County, Jiangsu Province, China
Shanghai Yuantai Chemical Products Co., Ltd

Contact:021--66129803

Address:Chengyin Road,Shanghai,China
Shao Xing Empire Import&Export CO.,ltd

Contact:86-575-82127757

Address:11#, Weiwu Road, Shangyu Industrial Park, Hangzhou Bay, Hangzhou, Zhejiang Province, China
XinChem Corporation

Contact:+86 21 34123252

Address:14, 4580 Dushi, Shanghai, China

Relevant to this article

Highly stereoselective synthesis of aminoglycosides via rhodium-catalyzed and substrate-controlled aziridination of glycals

Doi:10.1039/b823099b
(2009)
Synthesis and characterization of monomeric and polymeric Pd(II) and Pt(II) complexes of 3,4-ethylenedioxythiophene-functionalized phosphine ligands

Doi:10.1039/b817210b
(2009)
STEREOCHEMICAL STUDIES, 105. SATURATED HETEROCYCLES, 109 SYNTHESIS AND STERIC STRUCTURES OF PERHYDRO-4,1-BENZOXAZEPIN-2-ONES

Doi:10.1016/S0040-4020(01)90311-4
(1987)
SYNTHESIS OF (+/-)-PREPINNATERPENE, A BROMODITERPENE FROM THE RED ALGA LAURENCIA PINNATA YAMADA

Doi:10.1016/S0040-4039(00)96491-8
(1987)
Desulfurizative titanation of allyl sulfides. Regio and diastereoselective preparation of homoallyl alcohols

Doi:10.1016/0040-4039(95)00068-N
(1995)
Doi:10.1021/ja01199a600
(1947)

Article Doi