Reaction of 2-Diazopropane with an Arylsulphonyl-trimethylsilyl Substituted Alkene. Steric Control of Regiochemistry by the Trimethylsilyl Group

DOI: 10.1039/c39870001742

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1742 - 1743 (1987)

Update date:2022-08-16

Topics:

Authors:

Padwa, Albert

Wannamaker, M. Woods

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39870001742

The 1,3-dipolar cycloaddition of 2-diazopropane with trimethyl<3-(p-tolylsulphonyl-2,5-norbornadiene-2-yl)>silane occurs across the unsubstituted double bond; regiochemical control can be attributed to steric rather than to stereoelectronic factors.

Full text of DOI:10.1039/c39870001742

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:C₁₇H₂₂O₂SSi

Cas No:115134-53-7

R&D Labs maybe for 115134-53-7

Tianjin Hedong Red Cliff Chemical Reagent Factory

Contact:+86-022-84780548

Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
Taimai Sanluck Pharmaceutical Co.,Ltd

Contact:86-592-7662921

Address:8D,No.186,Huarong Road,Huli,Xiamen,China
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.

Contact:+86-186-02659358

Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China
Hubei Xiangxi Chemical Industry Co.,Ltd

Contact:+86-710-3454830

Address:No.7, Daqing East Road, Xiangfan City, Hubei Province, China
Shanghai Hanshare Industry Co.,Ltd.

Contact:86 21 20960688

Address:RM902-903,Building E, Wanda Plaza,No.26,Zhoukang Road, Pudong District, Shanghai, China

Relevant to this article

Highly stereoselective synthesis of aminoglycosides via rhodium-catalyzed and substrate-controlled aziridination of glycals

Doi:10.1039/b823099b
(2009)
Synthesis and characterization of monomeric and polymeric Pd(II) and Pt(II) complexes of 3,4-ethylenedioxythiophene-functionalized phosphine ligands

Doi:10.1039/b817210b
(2009)
STEREOCHEMICAL STUDIES, 105. SATURATED HETEROCYCLES, 109 SYNTHESIS AND STERIC STRUCTURES OF PERHYDRO-4,1-BENZOXAZEPIN-2-ONES

Doi:10.1016/S0040-4020(01)90311-4
(1987)
SYNTHESIS OF (+/-)-PREPINNATERPENE, A BROMODITERPENE FROM THE RED ALGA LAURENCIA PINNATA YAMADA

Doi:10.1016/S0040-4039(00)96491-8
(1987)
Desulfurizative titanation of allyl sulfides. Regio and diastereoselective preparation of homoallyl alcohols

Doi:10.1016/0040-4039(95)00068-N
(1995)
Doi:10.1021/ja01199a600
(1947)

Article Doi