Deracemization of 2-alkylcyclohexanones utilizing host-guest molecular association with optically active host compounds in basic suspension media

DOI: 10.1016/S0040-4039(97)10071-5

Source and publish data:

Tetrahedron Letters p. 7759 - 7760 (1997)

Update date:2022-08-28

Topics:

Authors:

Tsunoda, Tetsuto

Kaku, Hiroto

Nagaku, Miwa

Okuyama, Etsuko

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Article abstract of DOI:10.1016/S0040-4039(97)10071-5

Based on host-guest inclusion complexation in the solid state, α- substituted cyclohexanones 2α-c were deracemized using optically active host compounds in alkaline conditions to optically active 2 in excellent chemical yield with high enantiomeric excess.

Full text of DOI:10.1016/S0040-4039(97)10071-5

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