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Asymmetric Diels-Alder Reactions with Chiral 1-Azadienes

DOI: 10.1016/0957-4166(94)80017-0

Source and publish data:

Tetrahedron Asymmetry p. 557 - 560 (1994)

Update date:2022-08-29

Topics:

Authors:

Beaudegnies, RenaudBeaudegnies, Renaud

Ghosez, LeonGhosez, Leon

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Article abstract of DOI:10.1016/0957-4166(94)80017-0

Chiral 1-azadienes 1 derived from α,β-unsaturated aldehydes and Enders' hydrazines cycloadd to cyclic dienophiles with high facial selectivities.The adducts can be readily converted into enantiomerically pure piperidine derivatives. - Keywords: asymmetric cycloadditions, 1-azadienes, piperidines.

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Full text of DOI:10.1016/0957-4166(94)80017-0

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Product name:(S)-2-(1-METHOXY-1-METHYLETHYL)PYRROLIDINE

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