Bulletin of the Chemical Society of Japan p. 1419 - 1421 (1991)
Update date:2022-08-25
Topics:
Akaba, Ryoichi
Aihara, Shin
Sakuragi, Hirochika
Tokumaru, Katsumi
Anodic oxidation of 1,1-diphenyl-2-methylpropene (1) in an acetonitrile-methanol mixture under argon gave 3,3-diphenyl-2-butanone (2) in high yield together with small amounts of 1,2-diphenyl-2-methyl-1-propanone (3) and benzophenone (4).Similar anodic oxidation of 1 in the presence of oxygen was also carried out, and the mechanisms for the novel ketone forming reactions are discussed.
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