Binaphthol-derived Titanium μ-Oxo Complex: a New Type of Asymmetric Catalyst for Carbonyl-ene Reaction with Glyoxylate

DOI: 10.1039/c39940000833

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 833 - 834 (1994)

Update date:2022-08-29

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Authors:

Terada, Masahiro

Mikami, Koichi

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Article abstract of DOI:10.1039/c39940000833

The binaphthol (binol)-derived chiral titanium μ-oxo complex O is obtained accidentally upon toluene azeotropy from a solution of binol and (PrⁱO)2TiCl2 after filtration of ms 4 Angstroem and shown to be an efficient asymmetric catalyst for the

Full text of DOI:10.1039/c39940000833

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