Lewis acid promoted highly diastereoselective desymmetric intramolecular cyclization of allylstannane with a diketone

DOI: 10.1016/S0040-4039(97)10579-2

Source and publish data:

Tetrahedron Letters p. 471 - 474 (1998)

Update date:2022-07-29

Topics:

Authors:

Shimada, Takashi

Yamamoto, Yoshinori

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Article abstract of DOI:10.1016/S0040-4039(97)10579-2

The Lewis acid mediated desymmetric intramolecular cyclization of prochiral allylstannyl diketone 1 gave a mixture of two diastereomers 2 and 3. Highly diastereoselective synthesis of each diastereoisomer was accomplished by proper choice of the Lewis acids.

Full text of DOI:10.1016/S0040-4039(97)10579-2

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