Tetrahedron p. 5411 - 5416 (1987)
Update date:2022-08-15
Topics:
Pecunioso, Angelo
Menicagli, Rita
Diisobutylalkenylalanes, easily prepared by hydroalumination of terminal, α-branched and internal alkynes, react with α-nitroolefins to give pure E-γ-nitroolefins in almost quantitative yields.The reaction described is a convenient and simple approach to E-β,γ-unsaturated carbonyl compounds.
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