Journal of Materials Chemistry p. 357 - 363 (1996)
Update date:2022-08-28
Topics:
Sudhoelter, Ernst J. R.
Van Dijk, Marinus
Teunis, Cees J.
Sanders, Georgine M.
Harkema, Sybolt
Van De Velde, Gerrit M. H.
Schouten, Pieter G.
Warman, John M.
Nineteen novel alkyl substituted porphyrins have been synthesized and their thermal phase behaviour has been investigated in detail. Twelve compounds showed a reversible phase transition below the isotropization temperature. From time resolved microwave conductivity (TRMC) measurements and powder X-ray diffractometry it was concluded that the molecular packing does not change significantly at the lower phase transition temperature and that the porphyrin cores occupy isolated positions. Single X-ray diffraction measurements showed that the porphyrins are arranged in a layered structure and that the space between the layers is occupied by the alkyl substituents of the pyrrole units. The phase transitions at the lower temperature were therefore identified as changes in the crystal ordering of the porphyrins.
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